Ms. Kharybina was born in 1965 in Moscow.
She graduated from the Russian State Open Technical University of Railway Transport of the Ministry of Railways of the Russian Federation with a degree in Accounting and Audit as a qualified Economist.
She began her professional career in the railway sector in 1982.
She has been working at the Moscow Railway for 28 years. Ms. Kharybina has worked in the Accounting Department of the Moscow–Yaroslavl Branch, the Moscow-2 Locomotive Depot, the Moscow-3 Locomotive Depot and in the Passenger Service Directorate of the Moscow Railway. In 2003, she was appointed First Deputy Head of the Financial Service of the Moscow Railway.
2004–2005: Head of the Financial Service of the Moscow Railway.
2005–2010: Deputy Head of Economics and Finance of the Moscow Railway.
2010–2012: Deputy Managing Director for Economics and Finance of the Centre for Corporate Transport Services (a branch of Russian Railways).
2012: Appointed First Deputy Head of the Economics Department of JSC Russian Railways.
2012–2016: Deputy Head of Moscow Metro for Economics and Finance.
September 2016: Appointed Chief Accountant of JSC Russian Railways.